<CustomTaskbarLayoutCollection PinListPlacement="Replace">
    <defaultlayout:TaskbarLayout>
      <taskbar:TaskbarPinList>
        <taskbar:DesktopApp DesktopApplicationLinkPath="%APPDATA%\Microsoft\Windows\Start Menu\Programs\Accessories\Internet Explorer.lnk"/>
        <taskbar:DesktopApp DesktopApplicationLinkPath="%ALLUSERSPROFILE%\Microsoft\Windows\Start Menu\Programs\Accessories\Paint.lnk" />
        <taskbar:UWA AppUserModelID="Microsoft.Office.Word_8wekyb3d8bbwe!microsoft.word" />
      </taskbar:TaskbarPinList>
    </defaultlayout:TaskbarLayout>
  </CustomTaskbarLayoutCollection>